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What
is TDS?
Reprinted from the
Pool & Spa Service Industry News
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POOLS AND SPAS
"TDS: Check it out when the water
doesn't behave."
By David Dickman
Reprinted from Pool & Spa Service Industry News
TDS -
Total Dissolved Solids - may be the most misunderstood factor in the
whole field of pool & spa water chemistry. It is misunderstood
because no one knows exactly what effect it is going to
have on any particular body of water.
When everything else
seems to be all right, and the water still acts screwy, check the
TDS.
High TDS can result in
corrosion of metal equipment and accessories, even though the water
is balanced.
High TDS can cause eye
and skin irritation, even though the pH is right and there are no
chloramines in the water.
High TDS can permit an
algae bloom, even with a 2-3 ppm chlorine residual.
But none of these
symptoms will necessarily occur. It is the uncertain nature of
problems caused by TDS that makes it such a headache to deal with.
As its name states, TDS
is the sum total of all of the dissolved things in a given body of
water. It's everything in the water that's not actually water. It
includes hardness, alkalinity, cyanuric acid, chlorides, bromides,
sulfates, silicates, and all manner of organic compounds.
Every time you add
anything to the water, you are increasing its TDS. This includes
not only sanitizing and pH adjusting chemicals, but also
conditioner, algicides, and tile and surface cleaners. It includes
airborne pollutants and bather waste as well as dissolved minerals
in the fill water.
At low levels, TDS does
not present a problem. In fact, a certain amount of TDS is
necessary for water balance. Hardness and Total Alkalinity are
both part of TDS.
But at high levels -
above 3,000 parts per million - you are welcoming problems. The
National Spa & Pool Institute, in its standards for both swimming
pools and spas, recommends an ideal TDS of between 1,000 and 2,000
ppm, with a maximum of 3,000 ppm.
No one
knows exactly what mechanism is at work when you're dealing with
high TDS water. One commonly held theory is that when you get a lot
of dissolved substances in water, they interfere with the normal
workings of sanitizers. They may do this by forming a chemical
"shield" around bacteria, algae, and other substances normally
attacked by chlorine or bromine. Or they may simply present
"roadblocks" in the path of sanitizer molecules, preventing them
from freely circulating.
TDS
buildup is inevitable. As we've explained, every time you add
chemicals to water, you're increasing the TDS. When the water
evaporates, it leaves behind all of the solids that had been
dissolved in it.
Just how
much are you increasing the TDS when you chemically treat pool or
spa water? Well, for every pound of dry chemical that you add to a
15,000 gallon pool, you are increasing the TDS by about 8 ppm.
"Parts
Per Million" is what scientists refer to as a "weight to weight"
measurement. That is, if you know how much the water weighs, and
you know how much the stuff you are adding to the water weighs, you
can calculate how many parts per million you are adding to the
water.
As it
happens, one gallon of water weighs 8.34 pounds. So if you know how
many gallons are in a pool or spa, and you multiply that number by
8.34, you will know how many pounds of water are in the pool or spa.
So, how
many pounds of water are in a 450 gallon spa? The answer is 3,753
pounds (450 x 8.34 = 3,753). How about a 15,000 gallon pool? Well,
15,000 x 8.34 = 125,100. So, there are 125,100 pounds of water in a
15,000 gallon pool.
OK, so
now you know how much the water weighs. Now, take 1 million and
divide it by the total weight of that water, and you will find out
how many parts per million are contained in each pound of water.
For example, 1,000,000/125,100 (pounds of water in our 15,000 gallon
pool) = 7.99. We'll call it 8. That is, every pound of material
added to a 15,000 gallon pool will contribute about 8 parts per
million.
How about our 450 gallon spa? Take 1,000,000, divide it by 3,753
(the weight of the water in the spa), and you get 266.45. We'll
settle on 266. So for every pound of stuff that you add to a 450
gallon spa, you will be increasing the TDS by 266 parts per million.
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Effect of Dissolved Material on TDS - Pools
(How Much 1 Pound of Material
Will Raise TDS In Pools of Various Sizes) |
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Pool Capacity |
TDS per 1 Pound |
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5,000 gal. |
24 ppm |
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10,000 gal. |
12 ppm |
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15,000 gal. |
8 ppm |
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20,000 gal |
6 ppm |
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25,000 gal |
4.8 ppm |
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50,000 gal |
2.4 ppm |
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100,000 gal |
1.2 ppm |
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150,000 gal |
0.8 ppm |
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Effect of Dissolved Material on TDS -
Spas
(How Much 1 Pound of
Material Will Raise TDS In Pools of Various Sizes) |
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Pool Capacity |
TDS per 1 Pound |
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400 gal. |
300 ppm |
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450 gal. |
266 ppm |
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500 gal. |
240 ppm |
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550 gal |
218 ppm |
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600 gal |
200 ppm |
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650 gal |
184 ppm |
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700 gal |
171 ppm |
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750 gal |
160 ppm |
The
above charts should give you a pretty good idea of why TDS builds up
so rapidly in spa water and also why the effect of chemical
treatment is so dramatic when you are dealing with a spa. The
accompanying charts - one for pools and the other for spas - will
also give you an idea of how much of an impact 1 pound of chemical
added to the water will have on TDS in vessels of different sizes.
Incidentally, if you wanted to design a pool that would contain
almost exactly 1 million pounds of water, it would be a 120,000
gallon vessel. In that pool, every 1 pound of solids dissolved in
the water would increase the TDS by 1 ppm.
Every
sanitizing chemical, and every pH adjusting chemical used in the
pool and spa industry will eventually contribute to the TDS in a
pool or spa. Some will contribute more than others. Because
sanitizing compounds often require the additonal use of pH adjusting
chemicals, the chemical maintenance regimen you choose can have a
dramatic effect on the buildup of TDS.
TDS is
fairly easy to calculate for dry chemicals. It's a bit more
complicated for liquid solutions. If a research lab were going to
test the solids content of a liquid, they would take a precise
volume of the liquid and then slowly heat it until the liquid itself
had evaporated. Then they would dry the remaining solids and weight
them.
The two
most common liquid solutions used in our industry are muriatic acid
and liquid chlorine (sodium hypochlorite). For your information, 1
gallon of muriatic acid will contribute 1.87 pounds of dissolved
solids to the water. 1 gallon of liquid chlorine will contribute
2.2 pounds of dissolved solids.
You
should also understand that every type of chlorine & sanitizer -
including gas chlorine - eventually ends up contributing to TDS in
the form of chloride. So every time you add a pound of dry chlorine
compound, or infuse a pound of gas chlorine into a 15,000 gallon
pool, you will wind up increasing the TDS by about 8 ppm.
TDS
Testing
Short of a detailed laboratory analysis, the most dependable method
of TDS testing is through the use of a portable TDS meter. These
meters actually measure the conductivity of the water -
its ability to conduct an electrical charge, which happens to
increase as the TDS increases.
Hand-held TDS meters - usually in the $50.00 - $150.00 range,
gggeenerally operate by either placing some water in a sample cell
or dipping the meter directly in the pool water and pushing a
button, which causes a small electric current to pass between two
electrodes immersed in the water and separated by a specific
distance.
The meter measures the current passing between the electrodes and
uses that to deter mine the water's conductivity, the meter dial (or
LCD readout) is calibrated to indicate TDS in parts per million.
The easieste way to reduce TDS is to drain the pool and refill it
with fresh water. This can also be done in stages, taking the water
level down 1 or 2 feet at a time and refilling over a period of days
or weeks.
Under normal circumstances, pool water can be expected to last
anywhere from 3 to 5 years before it has to be completely changed.
Your choice of chemical treatment can help to determine just how
long it lasts.
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